Type
Analysis
Element
|
Min
|
Max
|
Carbon
|
--
|
0.02
|
Nickel
|
--
|
29.0
|
Iron
|
Balance
|
Silicon
|
--
|
0.20
|
Manganese
|
--
|
0.30
|
Cobalt
|
--
|
17.0
|
Description
Kovar alloy is a vacuum melted,
iron-nickel-cobalt, low expansion alloy whose chemical composition is
controlled within narrow limits to assure precise uniform thermal
expansion properties. Extensive quality controls are employed in the
manufacture of this alloy to ensure uniform physical and mechanical
properties for ease in deep drawing, stamping and machining.
Applications
Kovar alloy has been used for making
hermetic seals with the harder Pyrex glasses and ceramic
materials. This alloy has found wide application in power tubes,
microwave tubes, transistors and diodes. In intergrated circuits, it
has been used for the flat pack and the dual-in-line package.
Physical
Properties
Specific gravity.......................................8.36 Curie temperature
Density °F.................................................... 815
lb/cu in............................................... 0.302 °C.................................................... 435
kg/cu m............................................... 8359 Melting Point
Thermal conductivity °F.................................................. 2640
Btu-in/ft²/hr/°F...................................... 120 °C................................................. 1450
W/m-K.................................................. 17.3 Modulus of elasticity
Electrical resistivity psi x 10(6) ..................................... 20
ohm-cir mil/ft......................................... 294 MPa x 10(3) .................................. 138
microhm-mm......................................... 490
Magnetic
Properties
Kovar alloy is magnetic at all
temperatures below the Curie point. Magnetic properties will depend
upon heat treatment; the lower the hardness, the higher the
permeability values and lower hysteresis loss. Examples of
permeability properties are shown in the following chart:
Flux
Density
|
Treatment
|
1830°F
(999°C) 30 min. - FC Permeability
|
2010°F
(1099°C) 20 min. - FC Permeability
|
500 1000 2000 5000 10000 12000
|
1000 1400 2000 2300 3400 3000
|
1900 3500 5800 10000 8200 5000
|
Thermal
Expansion Properties
The following are the average
coefficient of expansion properties after annealing in hydrogen for 1
hr at 1650°F (900°C) and 15 minutes at 2010°F (1099°C)
and cooled to room temperature within 1 hr. Material heat treated
using this procedure should not exhibit any transformation when
cooled to -112°F (-80°C) for 4 hrs. This was determined by
means of metallographic examination. Mean coefficient of thermal
expansion as annealed.
Temperature
|
Coefficient
|
77°F to
|
25°C to
|
10(-6)/°F
|
10(-6)/°C
|
212 392 572 662 752 842 932 1112 1292 1472 1652
|
100 200 300 350 400 450 500 600 700 800 900
|
3.25 2.89 2.85 2.72 2.81 2.92 3.41 4.34 5.06 5.73 6.25
|
5.86 5.20 5.13 4.89 5.06 5.25 6.15 7.80 9.12 10.31 11.26
|
Preparation
for Sealing
All degreased, fabricated Kovar alloy
parts should be degassed and annealed in a wet hydrogen atmosphere.
Atmosphere is to be made moist by bubbling the hydrogen through water
at room temperature. Care must be taken to prevent surface carbon
pickup. Furnace should have a cooling chamber provided with the same
atmosphere. Heating should be conducted within the 1540/2010°F
temperature range. Time at temperature should be approximately two
hours for lowest temperature to 20 minutes for the highest
temperature. Parts should then be transferred to the cooling zone and
held until below 570°F, then removed. An oxide film on the
metallic part is preferred for metal-to-hard glass sealing. The best
oxide film is thin and tightly adhering. The film can be produced by
heating the parts to 1200/1290°F in regular ambient atmosphere
for a time sufficient to form a dark gray to slight brown oxide.
Workability
Forging The principal
precaution to observe in forging is to heat quickly and avoid soaking
in the furnace. Long soaking may result in a checked surface due to
absorption of sulfur from the furnace atmosphere and/or oxide
penetration. A forging temperature of 2000/2150°F is preferred.
Coolant It is important to
control heat build up, the major cause of warpage. A suggested
coolant would be Cool Tool. Cool Tool contains fatty esters to reduce
friction in the cutting zone and a refrigerant to remove the heat
generated by friction between the cutting tool and work place.
Tooling T-15 Alloy, such as
Vasco Supreme-manufactured by Vanadium Alloys Company. M-3 Type 2,
such as Van Cut Type 2-manufactured by Vanadium Alloys Company. Congo
manufactured by Braeburn. For machining with carbide tools, a K-6
manufactured by Kennemetal, Firthie HA manufactured by Firth
Sterling, or #370 Carboloy could be used, or a K2S manufactured by
Kennemetal, or Firthie T-04 manufactured by Firth Sterling would be
satisfactory. One thing of prime importance is that all feathered or
wire edges should be removed from the tools. They should be kept in
excellent condition by repeated inspection.
Turning If steel cutting
tools are used, try a feed of approximately .010" to .012"
per revolution and a speed as high as 35/FPM could probably be
attained. Some of the angles on the cutting tools would be as
follows:
End
cutting edge angle -Approximately 7°
Nose
radius -Approximately .005"
Side
cutting edge angle -Approximately 15°
Back
rake -Approximately 8°
Side
rake -Approximately 8°
When cutting off high speed tools are
better than carbide tools, and a feed of approximately .001" per
revolution should be used. The cutting tools should have a front
clearance of about 7° and a fairly big tip--larger than 25°
would be helpful.
Drilling When drilling a
3/16" diameter hole, a speed of about 40/FPM could possibly be
used, and the feed should be about .002" to .0025" per
revolution, for a 1/2" hole, approximately the same speed could
be used with a feed of about .004" to .005" per revolution.
The drills should be as short as possible, and it is desirable to
make a thin web at the point by conventional methods. By conventional
methods, we mean do not notch or make a crank shaft grinding. It is
suggested that heavy web type drills with nitrided or electrolyzed
surfaces be used. The hole, of course, should be cleaned frequently
in order to remove the chips, which will gall, and also for cooling.
The drill should be ground to an included point angle of 118° to
120°
Reaming Reaming speeds
should be half the drill speed, but the feed should be about three
times the drill speed. It is suggested that the margin on the land
should be about .005" to .010", and that the chamfer should
be .005" to .010" and the chamfer angle about 30°. The
tools should be as short as possible, and have a slight face rake of
about 5° to 8°.
Tapping In tapping, a tap
drill slightly larger than the standard drill recommended for
conventional threads should be used, because the metal will probably
flow into the cut. It is suggested that on automatic machines, a two
or three fluted tapping tool should be used. For taps below 3/16",
the two fluted would be best. Grind the face hook angle to 8° to
10°, and the tap should have a .003" to .005" chamfered
edge. If possible, if binding occurs in the hole in tapping, the
width of the land may be too great, and it is suggested that the
width of the heel be ground down. Again, it is suggested that
nitrided or electrolyzed tools be used. Speed should be about 20/FPM.
High
Speed Tool*
|
Turning And Forming
|
Cut-Off Tool
|
1/16"
|
SFM FEED
|
65 .0010
|
1/8"
|
SFM FEED
|
67 .0012
|
1/4"
|
SFM FEED
|
69 .0016
|
Tool Width
|
1/2"
|
SFM FEED
|
67 .0012
|
1"
|
SFM FEED
|
63 .0010
|
1-1/2"
|
SFM FEED
|
63 .0009
|
Drilling
|
Drill Dia.
|
3/8"
|
SFM FEED
|
43 .0030
|
3/4"
|
SFM FEED
|
45 .0036
|
Reaming
|
Under 1/2"
|
SFM FEED
|
57 .003
|
Over 1/2"
|
SFM FEED
|
57 .0045
|
Threading
|
T.P.I
|
3-7½ 8-15
|
SFM SFM
|
8 10
|
Over 16
|
SFM
|
16
|
Tapping
|
T.P.I
|
3-7½ 8-15 16-24
|
SFM SFM SFM
|
6 7 11
|
Over 25
|
SFM
|
16
|
Milling
|
|
SFM FEED
|
35-70 .002-.005
|
Broaching
|
|
SFM FEED
|
8-12 .001-.005
|
Turning Single
Point & Box Tools
|
High Speed Tools
|
SFM FEED
|
60-65 .0029-.0043
|
Carbide Tools
|
SFM FEED
|
160-215 .025-.080
|
*When using carbide tools,
surface speed feet/minute (SFM) can be increased between 2 and 3
times over the high speed suggestions. Feeds can be increased
between 50 and 100%.
Note: Figures used for all metal
removal operations covered are average. On certain work, the nature
of the part may require adjustment of speeds and feeds. Each job has
to be developed for best production results with optimum tool life.
Speeds or feeds should be increased or decreased in small steps.
The information and data
presented herein are typical or average values and are not a
guarantee of maximum or minimum values. Applications specifically
suggested for material described herein are made solely for the
purpose of illustration to enable the reader to make his own
evaluation and are not intended as warranties, either express or
implied, of fitness for these or other purposes.
Typical
Mechanical Properties
Typical Mechanical Properties of
Strip Tested parallel to the direction of rolling. Material
annealed 1830°F for 30 minutes, then furnaced cooled.
Yield Strength
|
Tensile Strength
|
%
Elongation in 2"
|
Hardness Rockwell
B
|
ksi
|
MPa
|
ksi
|
MPa
|
50
|
345
|
75
|
517
|
30
|
68
|
|