Type
Analysis
Element
|
Min
|
Max
|
Carbon
|
0.15
|
0.20
|
Manganese
|
--
|
0.50
|
Silicon
|
--
|
0.50
|
Phosphorus
|
--
|
0.03
|
Sulfur
|
--
|
0.03
|
Chromium
|
12.00
|
14.00
|
Nickel
|
1.80
|
2.20
|
Molybdenum
|
--
|
0.50
|
Tungsten
|
2.50
|
3.50
|
Iron
|
Balance
|
Description
Greek Ascoloy (418) is a
hardenable chromium-nickel-tungsten martensitic alloy that is
designed for services at temperatures up to 1200 °F in highly
stressed parts. This steel is an extremely deep-hardening grade
and is used where slightly superior creep strength and resistance to
tempering and stress-corrosion cracking are desired in addition to
the general properties of the 12% chromium stainless steels. Typical
applications are steam turbine buckets and blades as well as
compressor parts in gas turbines and high temperature bolts.
Corrosion
Resistance
Greek Ascoloy has good
resistance to scaling and oxidation at temperatures up to 1400 °F.
It resists atmospheric corrosion, weak organic acids and oxidizing
acids. It has best corrosion resistance in the hardened and tempered
condition.
Physical
Properties
Specific gravity..............................................7.874
Density
lb/in(3)........................................................0.2864
kg/m(3)....................................................... 79164
Electrical resistivity-77 °F (25.0 °C)4
ohm-cir mil/ft............................................... 4754
microhm-mm................................................ 7904
Melting range °F.....................................600/27004
°C ................................. 1427/1482
Modulus of Elasticity in
Tension (E)
Temperature
|
psi
x 10(6)
|
MPa
x 10(3)
|
°F
|
°C
|
70 1000 1100
|
21.1 538 593
|
29.0 21.5 17.0
|
199 148 117
|
Coefficient of
Thermal Expansion
Temperature
|
Coefficient
|
80 °F to
|
26.7 ° C to
|
10(-6)/° F
|
10(-6)/° C
|
200 400 600 800 1000 1100 1200
|
93 204 316 427 538 593 649
|
5.83 6.12 6.20 6.37 6.52 6.62 6.63
|
10.5 11.0 11.2 11.5 11.7 11.9 11.9
|
Heat
Treatment
Annealing Greek
Ascoloy (418) is process annealed by heating to 1300 °F, holding
at temperature approximately 4 hours, and air cooling. The resultant
hardness is approximately 280 BHN. To obtain maximum softness and
complete relief of stresses, a cyclic anneal is required. This
treatment consists of heating to 1450 °F for 2 to 4 hours
followed by furnace cooling to 800 °F least 200 °F. The
material is then reheated to 1250/1300 °F for a minimum of 12
hours and air cooled. The resultant hardness is approximately 255
BHN.
Hardening and
Tempering An austenizing temperature of 1700/1800 °F is
generally used to harden Greek Ascoloy (418) followed by quenching in
either oil or air depending upon section size and design. Heavy
sections, or parts of intricate design are usually preheated at
1200/1400 °F prior to hardening. The resultant hardness is
approximately 448/472 BHN. Tempering should be done as soon as
possible following the hardening treatment. The effect of tempering
temperature on hardness after oil treating from 1750 °F is shown
below.
Tempering Temperature 2
hours
|
Hardness
BHN
|
°F
|
°C
|
1050 1150 1200 1250 1300
|
566 621 649 677 704
|
364 302 297 285 280
|
Workability
Hot Working Greek
Ascoloy is readily hot worked in the temperature range 1750/2150°F.
Large sections should be preheated to 1200/1400°F prior to
heating to forging or rolling temperature. Forgings should be cooled
slowly from hot working temperatures.
Machining Greek
Ascoloy is readily machinable in the annealed condition and is
comparable with types 403 and 410.
Welding The
air-hardening qualities of this steel favor preheating to 400/600°F.
Annealing as soon as possible after welding is recommended because of
the air-hardening characteristics which make the heat affected zone
hard and brittle. An austenitic steel filler rod such as Type 310
stainless is recommended in order to obtain sufficient ductility in
the weld.
Typical
Mechanical Properties
Typical Room
Temperature Tensile Properties Specimens heat treated by
hardening at 1750°F and oil quenching followed by tempering at
temperature indicated for 4 hours and air cooling.
Tempering Temperature
|
Yield
Strength
|
Ultimate Tensile Strength
|
% Elongation in
2"
|
% Reduction of
Area
|
°F
|
°C
|
0.2% offset
|
0.02% offset
|
|
|
ksi
|
MPa
|
ksi
|
MPa
|
ksi
|
MPa
|
500 600 700 800 900 1000 1100 1200 1300
|
260 316 371 427 482 538 593 649 704
|
175 180 183 185 165 137 120 108 98
|
1207 1241 1262 1276 1138 945 827 745 676
|
150 160 165 168 158 140 123 107 87.5
|
1034 1103 1138 1158 1089 965 848 738 603
|
209 212 217 217 197 165 145 135 125
|
1441 1462 1496 1496 1358 1138 1000 931 862
|
18.0 17.0 16.0 16.0 17.0 17.5 18.0 20.0 22.0
|
53.0 55.0 56.0 57.0 58.0 59.0 60.0 61.0 62.0
|
Typical Short-Time Elevated Temperature Tensile Properties Specimens heat-treated by hardening at 1750°F (954°C), oil quench followed by tempering at 1050°F (566°C), air cool.
Test Temperature
|
Yield
Strength 0.2% offset
|
Ultimate Tensile Strength
|
% Elongation in
2" (50.8 mm)
|
% Reduction of
Area
|
°F
|
°C
|
ksi
|
MPa
|
ksi
|
MPa
|
70 500 600 800 900 1000
|
21 260 316 427 482 538
|
135 129 124 112 101 84
|
931 889 855 772 696 579
|
160 150 144 127 113 95
|
1103 1034 993 876 779 655
|
16 12 11 10 13 17
|
45 43 43 43 52 64
|
Specimens heat treated by hardening at 1750°F (954°C), oil quench followed by tempering at 1200°F (649°C), air cool.
Test Temperature
|
Yield
Strength 0.2% offset
|
Ultimate Tensile Strength
|
% Elongation in
2" (50.8 mm)
|
% Reduction of
Area
|
°F
|
°C
|
ksi
|
MPa
|
ksi
|
MPa
|
70 900 1000 1100
|
21 482 538 593
|
115 82 70 55
|
793 565 483 379
|
140.8 100 84 67
|
971 689 579 462
|
21.0 16.0 22.0 30.0
|
58.0 63.0 74.0 83.0
|
Room Temperature Impact Strength - Izod V-Notch Specimens heat treated by hardening at 1750°F (954°C) and oil quenching.
Tempering Temperature
|
Impact Strength
|
°F
|
°C
|
ft-lb
|
J
|
500 600 700 800 900 1000 1100 1200 1300
|
260 316 371 427 482 538 593 649 704
|
19 16 10 9 10 17 40 77 65
|
26 22 14 12 14 23 54 104 88
|
Hot Hardness Specimens heat treated by hardening at 1750°F (954°C), air cool followed by tempering at 1000°F (538°C), 2 hrs., air cool.
Test Temperature
|
Hardness BHN 30 min. at Temperature
|
°F
|
°C
|
700 800 1000 1200
|
21 427 538 649
|
352 312 290 176
|
Stress Rupture
Properties Specimens heat treated by hardening at 1800°F,
air cool followed by tempering at 1050°F, 2 hrs, air cool.
Test Temperature
|
Stress
for Rupture in
|
°F
|
°C
|
10 hours
|
100 hours
|
1000 hours
|
ksi
|
MPa
|
ksi
|
MPa
|
ksi
|
MPa
|
1000 1100 1200
|
538 593 649
|
65 42 23
|
448 290 159
|
52 33 19
|
359 228 131
|
41 22 11
|
283 152 76
|
|