Type
Analysis
Element
|
Min
|
Max
|
Carbon
|
--
|
0.03
|
Manganese
|
8.00
|
10.0
|
Silicon
|
--
|
1.00
|
Sulfur
|
--
|
0.03
|
Nickel
|
5.50
|
7.50
|
Chromium
|
19.0
|
21.5
|
Nitrogen
|
0.15
|
0.40
|
Phosphorus
|
--
|
0.04
|
Description
21Cr-6Ni-9Mn is a high maganese
nitrogen strengthened, austenitic stainless steel that combines high
strength in the annealed condition, excellent resistance to oxidation
at high temperatures, good resistance to lead oxide and a high level
of corrosion resistance at ambient temperatures. The alloy can be
fabricated and formed much the same as Type 304 and 316, and is
readily weldable. It remains nonmagnetic after severe cold
work. 21Cr-6Ni-9Mn has been used for chemical process and
pollution-control equipment, steam and autoclave applications, and
various aircraft engine components, as well as numerous other
applications.
Corrosion
Resistance
21Cr-6Ni-9Mn has corrosion resistance
approaching that of Type 304L. Its low carbon content provides
resistance to intergranular corrosion even in the welded condition.
For optimum corrosion resistance, surfaces must be free of scale and
foreign particles and finished parts should be passivated.
Typical Corrosion
Properties Annealed condition
Environment*
|
Material
Condition
|
Average Corrosion
Rate
|
65 w/o HNO3
- boiling 65 w/o HNO3 - boiling
5
w/o H2SO4 - R.T. 10
w/o acetic acid - boiling 10 w/o acetic acid - boiling Oxalic
acid etch test**
|
Annealed Annealed
+ Sensitized 1250°F (677°C) Annealed Annealed Annealed
+ Welded Annealed
|
7
mpy 9mpy
nil nil nil pass
|
*5 periods-48 hours
each **ASTM A262 Practice A
Scaling
21Cr-6Ni-9Mn has good resistance to
high temperature oxidation in air and to corrosion by molten lead
oxide.
Physical
Properties
Specific gravity .................................. 7.83
Density
lb/cu in ............................................. 0.283
kg/cu m ............................................. 7830
Mean specific heat
Btu/lb-°F(32/212°F) .......................... 0.12
J/kg-K(0-100°C) ................................. 500
Electrical resistivity (RT)
ohm-cir mil/ft ...................................... 439
microhm-mm ....................................... 730
Modulus of elasticity (E)
ksi ........................................... 28.5 x 10(3)
MPa ...................................... 196.5 x 10(3)
Mean Coefficient of Thermal Expansion
Temperature
|
10(-6)/°F
|
10(-6)/K
|
80°F to
|
27°C to
|
200 400 600 1000 1200 1600 1800
|
93 204 316 538 760 871 982
|
9.3 9.6 10.1 10.6 11.1 11.2 11.4
|
16.7 17.3 18.2 19.1 20.0 20.2 20.5
|
Thermal Conductivity
Test Temperature
|
Btu-in/ft²-hr-°F
|
W/m-K
|
°F
|
°C
|
200 400 600 800 1000 1200 1400 1600
|
93 204 316 427 538 649 760 871
|
96 112 126 140 156 172 186 200
|
14 16 18 20 23 25 27 29
|
Magnetic Permeability
Condition
|
Test Temperature
|
Field
Strength (oersteds) of
|
°F
|
°C
|
50
|
100
|
200
|
500
|
Annealed Annealed 15%
cold reduced 35% cold reduced 60% cold reduced
|
75 -350 75 75 75
|
24 -212 24 24 24
|
1.005 -- 1.004 1.005 1.010
|
1.004 -- 1.004 1.005 1.010
|
1.004 -- 1.003 1.005 1.012
|
1.002 1.005 -- -- <1.020
|
Heat
Treatment
Stress Relieving Stress
relieving is used to achieve best all-around properties and for
operating temperatures below 1300°F. The temperature range for
stress relieving is 900/1400°F. Temperatures between 900 and
1250°F will have little effect on the mechanical properties of
cold reduced material unless the percent cold reduction is high; then
slight increases or decreases in strength will occur. Above 1250°F,
the change in mechanical properites will occur more rapidly; a
temperature of 1500°F begins to cause rapid softening. The proper
stress relief treatment should be selected carefully in order to
produce the desired strength levels.
Annealing Annealing
is used for best stress rupture life and for operating temperatures
between 1300 and 1600°F. The alloy is not recommended for service
above 1600°F. Also, annealing softens the alloy for maximum
formability. After the annealing the strength of the material can be
increased only by hot/cold working or cold working. Annealing is
generally done in the temperature range of 1800/2150°F. Grain
coarsing will occur at the higher temperatures. Lower temperatures
such as 1650°F can be used; the temperature must be selected
according to the degree of softening required and grain size
restrictions.
Workability
Hot Working 21Cr-6Ni-9Mn
can be forged, hot rolled, hot headed and upset. An initial forging
temperature of 2100/2200°F is normally used. Preheating to an
intermediate temperature is not required. Forging can be rapidly
cooled without danger of cracking. This alloy can be hot worked as
low as 1200°F, and is not susceptible to hot shortness in the
entire working range. For best corrosion resistance, anneal after
forging.
Cold Working This alloy is
readily cold worked by conventional methods. The alloy's high
work-hardening rate and higher initial yield strength dictate greater
force than when forming the same part from Type 301, 302, 304, 316,
etc.
Hot/Cold Working This alloy
is a solution strengthened alloy and cannot be strengthened by heat
treatment. Hot/cold working or cold working can be employed to
strengthen this alloy. Hot/cold working is normally done in the
temperature range of 1200/1500°F ; reductions in the order of 10
to 14% are used and the percent used is dependent on the strength
level required. A stress relief of 900/1400°F is normally applied
after hot/cold working operations. Heat treatment of hot/cold worked
material, as discussed in the preceding section, will aid in
adjusting mechanical properties to the desired levels.
Machining 21Cr-6Ni-9Mn is
readily machined using the techniques applied to the austenitic
stainless steels. A rigid setup and ample coolant flow should be
considered.
Welding 21Cr-6Ni-9Mn can be
satisfactorily welded by the shielded fusion and resistance welding
processes. Oxyacetylene welding is not recommended., since carbon
pickup in the weld may occur. When a filler metal is required,
consider AWS E/ER219 welding consumables which should provide welds
with strength approaching that of the base metal. If high weld
strength is not necessary, then E/ER309 should be considered.
Resistance to intergranular corrosion can be restored by a postweld
annealing treatment.
Typical
Mechanical Properties
Effect of Annealing Temperature on
Typical Room Temperature Mechanical Properties of Strip
Annealing* Temperature
|
0.2% Yield
Strength
|
Ultimate Tensile
Strength
|
%
Elongation in 2"
|
Rockwell
B Hardness
|
°F
|
°C
|
ksi
|
MPa
|
ksi
|
MPa
|
1800 1850 1900 1950
|
982 1010 1038 1066
|
70 65 62 61
|
483 448 428 421
|
115 112 110 107
|
793 772 758 738
|
44 46 47 48
|
95 93 92 90
|
* Annealing time was
approximately 6 minutes
Typical Elevated Temperature
Tensile Properties of Anneal Strip
Test Temperature
|
0.2% Yield Strength
|
Ultimate Tensile
Strength
|
%
Elongation in 2"
|
Rockwell
B Hardness
|
°F
|
°C
|
ksi
|
MPa
|
ksi
|
MPa
|
75 200 400 600 800 900 1000 1100 1200 1300
|
24 93 204 316 427 482 538 593 649 704
|
65 52 41 38 32 29 29 28 26 26
|
448 359 283 262 221 200 200 193 179 179
|
112 100 89 86 79 75 71 68 60 51
|
1404 1253 614 593 545 517 490 469 414 352
|
42 41 40 33 33 41 35 35 26 24
|
95 -- -- -- -- -- -- -- -- -- --
|
Typical Stress Rupture Strength of
Annealed Strip
Test Temperature
|
Stress
for Rupture in
|
°F
|
°C
|
100 Hours
|
1000 Hours
|
ksi
|
MPa
|
ksi
|
MPa
|
1200 1500
|
649 816
|
32 6
|
221 40
|
32 3
|
152 21
|
|